Fair Look at Coordination Oligomerization of Higher α-Olefins

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Kinetic and microstructural studies of Cp2ZrCl2 and Cp2HfCl2-catalyzed oligomerization of higher α-olefins in mPAO oil base stocks production

Herein a quenched-flow kinetic technique was applied to calculate the rate constants of 1-hexene and 1-octene oligomerization catalyzed by the Cp2ZrCl2 and Cp2HfCl2/MAO catalyst systems, and subsequently a mechanism for the higher α-olefin oligomerization reaction was proposed. The oligomerization results showed that Zr-based catalyst in the oligomerization of 1-octene had the highest activity ...

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ژورنال

عنوان ژورنال: Polymers

سال: 2020

ISSN: 2073-4360

DOI: 10.3390/polym12051082